May 11, 2023 Leave a message

Mechanical properties of metal materials and knowledge of heat treatment process

 

The mechanical properties of metal materials refer to the behavior of metal materials under the action of external load or the combined action of load and environmental factors (temperature, medium and loading rate).
Common mechanical properties of metals are shown in the table below:

Metal Mechanical Properties

Commonly used metal mechanical properties index

strength

Yield strength, tensile strength, breaking strength

Plasticity

Elongation, reduction of area, strain hardening index

elasticity

Elastic modulus (stiffness), elastic limit, proportional limit

hardness

Brinell hardness, Vickers hardness, Rockwell hardness

toughness

Static toughness, impact toughness, fracture toughness

fatigue

Fatigue strength, fatigue life, fatigue notch sensitivity

stress corrosion

Stress corrosion critical stress field intensity factor, stress corrosion crack growth rate


Tensile stress-strain curve of low carbon steel under uniaxial static load


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Mild Steel Tensile Force-Elongation Curve

1. Section oa: elastic deformation

2. Section ab: elastic deformation + plastic deformation

3. Bcd section: obvious plastic deformation, yield phenomenon, and the continuous elongation of the sample under the condition that the force remains basically unchanged

4. dB segment curve: elastic deformation + uniform plastic deformation

5. Point B: necking phenomenon occurs, the local section of the sample is obviously reduced, the bearing capacity of the sample is reduced, the tensile force reaches the maximum value, and the sample is about to break.

strength index

Strength refers to the ability of a material to resist plastic deformation and fracture.

1. Yield strength

σs = Fs/S0

Fs: the tensile force (N) that the sample bears when it yields; S0: the original cross-sectional area of the sample (mm).

2. Tensile strength

The maximum tensile stress that the sample bears before breaking reflects the maximum uniform deformation resistance of the material.

σb = Fb/S0

σb is often used as the basis for material selection and design of brittle materials.


Plastic index

Plasticity is the ability of a material to undergo plastic deformation under static load without failure.

1. Elongation after break

The percentage of the elongation of the gauge length after the sample is broken to the original gauge length.

δ=(L1-L0)/L*100%

L0: gauge length; L1: gauge length of the test piece after breaking.

2. Reduction of area

The percentage of the maximum reduction of the cross-sectional area at the retracted item of the sample to the original cross-sectional area.

Ψ=(A0-A1)/A0 *100%

A0: The original cross-sectional area of the specimen; A1: The cross-sectional area of the necking after fracture.


strength index

Strength refers to the ability of a material to resist plastic deformation and fracture.

1. Yield strength

σs = Fs/S0

Fs: the tensile force (N) that the sample bears when it yields; S0: the original cross-sectional area of the sample (mm).

2. Tensile strength

The maximum tensile stress that the sample bears before breaking reflects the maximum uniform deformation resistance of the material.

σb = Fb/S0

σb is often used as the basis for material selection and design of brittle materials.


Plastic index

Plasticity is the ability of a material to undergo plastic deformation under static load without failure.

1. Elongation after break

The percentage of the elongation of the gauge length after the sample is broken to the original gauge length.

δ=(L1-L0)/L*100%

L0: gauge length; L1: gauge length of the test piece after breaking.

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2. Reduction of area

The percentage of the maximum reduction of the cross-sectional area at the retracted item of the sample to the original cross-sectional area.

Ψ=(A0-A1)/A0*100%

A0: The original cross-sectional area of the specimen; A1: The cross-sectional area of the necking after fracture.


Elasticity Index

Stiffness: The ability of a material to resist elastic deformation when stressed.

E=σ/ε

σ: tensile stress; ε: tensile strain

The microstructure is not sensitive to the mechanical performance index, and alloying, heat treatment, and cold plastic deformation have little effect on it.

Important mechanical performance indicators for material selection of mechanisms and components:

►The driving beam should have sufficient rigidity, otherwise it will cause vibration due to excessive deflection when lifting heavy objects.

►Machine tool and press spindle, bed and workbench have requirements for rigidity to ensure machining accuracy.

►Main components such as internal combustion engines, centrifuges and compressors must have sufficient rigidity to prevent vibration.


hardness

The ability of the local surface of a material to resist plastic deformation and failure.

It is an index to measure the softness and hardness of the material, and its physical meaning is related to the test method.

Hardness testing methods: Brinell hardness, Rockwell hardness, Vickers hardness, Shore hardness, Leeb hardness, Mohs hardness

(1) Brinell hardness

The average stress per unit area, that is, the quotient of the test force p and the spherical surface area of the indentation.

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< 450HB: The test indenter is a quenched steel ball, the hardness symbol is HBS;

<650HB: The test indenter is cemented carbide, and the hardness symbol is HBW.

Empirical formula:

Low carbon steel: σb≈3.6HBS;

High carbon steel: σb≈3.4HBS.

Scope of application: used to measure gray cast iron, structural steel, non-ferrous metals and non-metallic materials, etc.

Advantages and disadvantages:

The measured value is more accurate and repeatable;

Measurable tissue inhomogeneous materials;

Not suitable for testing finished products and thin parts;

Measurement is time-consuming and inefficient.

(2) Rockwell hardness

The hardness value of the material is expressed by measuring the indentation depth, and every 0.002mm is equivalent to 1 Rockwell hardness unit.

There are two types of indenters:

1. Diamond cone with cone angle α=120°,

2. A small quenched steel ball with a diameter of Φ1.588mm.

Rockwell hardness calculation formula:

HR=(k-h)/0.002

Indenter 1: k=0.2mm; Indenter 2: k=0.26mm.

ruler

hardness symbol

Head type

Total test force F/N

Measuring hardness range

Application examples

C

HRC

Diamond cone

1471

20-70

Hardened steel, high hardness cast iron, pearlitic malleable cast iron

B

HRB

Φ1.588mm steel ball

980.7

20-100

Mild steel, copper alloy, ferritic malleable iron

A

HRA

Diamond cone

588.4

20-88

Carbide, Hardened Sheet Steel, Case Hardened Steel

Advantages and disadvantages:

The test is simple, convenient and fast;

The indentation is small, and the finished product and thin parts can be measured;

The data is not accurate enough, three points should be measured to take the average value;

Inhomogeneous materials such as cast iron should not be tested.

(3) Vickers hardness

The hardness value is calculated according to the test force per unit area of the indentation.

The indenter is a diamond quadrangular pyramid with an included angle of 136° between two opposite surfaces.

Measuring range :

It is often used to measure thin parts, coatings, surface layers after chemical heat treatment, etc.

Advantages and disadvantages:

Accurate measurement and wide range of applications (hardness from extremely soft to extremely hard);

Measurable finished products and thin parts;

The surface requirements of the sample are high and labor-intensive.


Impact toughness

The ability of a material to resist damage under impact loads.

The impact energy Ak consumed when the sample breaks is:

Ak = mgH – mgh (J)

The impact toughness value ak is the impact energy consumed per unit cross-sectional area at the notch of the sample.

ak = Ak / S0 (J/cm²)

Low ak value - brittle material:

No obvious deformation when broken, metallic luster, crystalline.

High ak value - tough material:

Obvious plastic change, the fracture is gray and fibrous, dull.

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Fracture toughness

Fracture Mechanics: On the premise of acknowledging the existence of macroscopic cracks in machine parts, various new mechanical parameters of crack propagation are established, and the fracture criterion and material fracture toughness of cracked bodies are proposed.

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fatigue

Fatigue phenomenon:

The fracture phenomenon caused by cumulative damage of metal parts or components under the long-term action of fluctuating stress and strain.

Fatigue Features:

(1) Fatigue is a low-stress cycle time-delayed fracture, and the fracture stress is often lower than the tensile strength of the material, or even the yield strength;

(2) Fatigue is a brittle and sudden fracture, and there will be no obvious signs of deformation before the fracture, which is very dangerous;

(3) Fatigue is very sensitive to notches, cracks and structural defects, and is highly selective.

Fatigue limit σ-1:

The highest stress value at which a material undergoes numerous stress cycles without fatigue fracture.

Condition fatigue limit:

The maximum stress value that can withstand 107 stress cycles without breaking.

Empirical formula of steel fatigue strength:

σ-1= (0.45~0.55)σb

or σ-1= 0.27(σs+σb)

σ-1p= 0.23(σs+σb)

 

02
heat treatment process

Definition: The process of changing the internal structure of solid metal or alloy through heating, heat preservation and cooling to obtain the required properties.

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Purpose: One is to improve the process performance of materials and ensure the smooth progress of subsequent processing. This heat treatment is called pre-heat treatment; the other is to improve the performance of materials and prolong the service life of parts. This heat treatment is called final heat treatment.

Heat treatment classification:

Ordinary heat treatment (four fires: annealing, normalizing, quenching, tempering)

Surface heat treatment (surface quenching, chemical heat treatment)

Other heat treatment (vacuum heat treatment, deformation heat treatment, etc.)

Microstructural transformation of eutectoid steel during heating

Four steps in the transformation process of pearlite to austenite:

(1) Austenite nucleation;

(2) Austenite growth;

(3) The remaining Fe3C dissolves;

(4) Homogenization of austenite.
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Structural transformation of steel during cooling

Cooling transformation of austenite: Austenite is a stable phase above the critical point A1, and it becomes an unstable phase when it is cooled below A1, and the structure transformation will occur.

Importance: Determines the structure and properties of steel after heat treatment. For the same steel, the heating temperature and holding time are the same, but the cooling method is different, and the properties after heat treatment are completely different.

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Mechanical properties of 45 steel heated to 840°C and cooled under different cooling conditions

cooling method

σb/Mpa

σs/Mpa

δ/%

ψ/%

HRC

Cooling with the furnace

519

272

32.5

49

15~18

air cooling

657~706

333

15~18

45~50

18~24

cooling in oil

882

608

18~20

48

40~50

water cooling

1078

706

7~8

12~14

52~60

Establishment of isothermal transformation curve of supercooled austenite in eutectoid steel (metallographic hardness method)

Also known as "TTT curve" (Time-Temperature-Transformation Curve), because the shape is similar to "C", it is often called "C curve".

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With the help of the "C curve", it is possible to understand what kind of structure austenite transforms into under different cooling conditions and the properties of the transformed products, providing a theoretical basis for the correct formulation and selection of heat treatment processes.

Eutectoid steel C curve and transformation products

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1) Pearlite type transformation (also known as high temperature transformation)

Transformation temperature: A1~550℃; transformation product: pearlite

A1~6500℃: the pearlite sheet is thicker, P (pearlite-pearlite)

6500℃~6000℃: Pearlite layer is thinner, S (Sorbite-sorbite)

6000℃~5500℃: the pearlite layer is very fine, T (troolstite)

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The thickness of the ferrite and cementite lamellar layers of pearlite is related to the transformation temperature. The lower the temperature, the finer the pearlite lamellae. The layers become thinner, the strength and hardness increase, and the plastic toughness increases.

2) Bainitic transformation (also known as medium temperature transformation)

Transition temperature: 550-Ms (230°C)

Transformation product: Bainite B (bainite) - a mixture of supersaturated F and cementite.

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550~350℃: upper bainite (upper B) feathery structure, low strength and plasticity, high brittleness.

350℃~ Ms: lower bainite (lower B) needle-like structure, good comprehensive performance.

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3) Martensitic transformation (also known as low temperature transformation)

Transition temperature: Ms (230°C) ~ Mf

Transformation product: martensite (martensite) + A'(residual austenite)

Martensite: A supersaturated solid solution of carbon formed in α-Fe, represented by M.

Classification:

Low carbon martensite (low carbon martensite): Lath-like, with high strength and ductility. Also known as lath M (lath martensite).

High carbon martensite (high carbon martensite): lenticular, sheet-like, with ridges in the middle. It has high strength, but poor ductility and high brittleness.

Image] [image

C curve of hypoeutectoid steel

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C curve of hypereutectoid steel

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Supercooled austenite continuous transformation cooling curve (CCT curve) (Continuous Cooling Transformation)

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annealing

Definition: Heating metal to a certain temperature, maintaining it for a sufficient time, and then cooling it at an appropriate rate

Purpose:

refine grains;

Reduce the hardness and improve the forming and cutting performance of steel;

Eliminate internal stress.

Classification: According to the purpose and process characteristics of annealing, it can be divided into complete annealing, incomplete annealing, isothermal annealing, spheroidizing annealing, stress relief annealing, etc.

full annealing

l Scope of application: hypoeutectoid steel

lHeating temperature: Ac3+30~50℃

l Purpose: to refine the structure, reduce the hardness, improve machinability,

Eliminate internal stress

l Room temperature tissue: F+P
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Spheroidizing annealing

Scope of application: eutectoid steel and hypereutectoid steel

Heating temperature: Ac1+20~30℃

Purpose: to spheroidize reticular or flake Fe3CⅡ

Organization: spherical pearlite

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isothermal annealing

Process: Heating to Ac1+30~50°C or Ac3+30~50°C, after keeping warm, quickly cooling to a temperature below Ar1, when A has turned into P-type tissue, take it out of the furnace and air-cool.

Organization: Class P

Advantages: short annealing time, uniform structure

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Relief annealing

Purpose: to remove residual stress

heating

Temperature: T heating < AC1 (500 ~ 600 ℃)

Application: Eliminate residual internal stress of castings, forgings, weldments, etc.

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Homogenization annealing (diffusion annealing)

Purpose: Eliminate segregation; uniform composition, organization

Heating temperature: AC3+150~250℃

Organization: hypoeutectoid steel is P+F.

Application: Mainly used for alloy steel ingots, castings and forgings with high quality requirements.

Recrystallization annealing

Process: Heating to 50-150°C below Ac1, or T+30-50°C, keeping warm and cooling slowly.

Purpose: Eliminate work hardening and restore the plasticity and toughness of steel.

Application: Eliminate work hardening of workpieces after cold working. Such as the annealing in the middle of the steel wire drawing process.


Normalizing

Definition: A heat treatment process in which the workpiece is heated to 30-50°C above Ac3 or Accm, taken out of the furnace after heat preservation, and cooled in air.

Purpose:

Low carbon steel: increase hardness and facilitate cutting.

Hypereutectoid steel: Eliminate reticular secondary cementite, which is beneficial to P spheroidization.

Medium-carbon steel and medium-carbon low-alloy steel: the stress is not large, and the performance requirements are not high, which can be used as the final heat treatment.

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Quenching

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Purpose: To obtain the structure under M or B, and improve the hardness and wear resistance of steel.

Selection of quenching temperature

Hypoeutectoid steel: AC3+30~50 ℃;

Eutectoid steel and hypereutectoid steel: AC1+30~50℃.

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Quenching cooling is the key to determining the quality of quenching, and the ideal cooling rate should be as shown in the figure.

Above 650℃, slow, reduce thermal stress

650-400 ℃, fast, avoid C curve

Below 400 ℃, slow, reduce phase transition stress

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Commonly used quenching medium

At present, the commonly used cooling media in production are oil, water, and brine, and their cooling capacity increases sequentially.

Water: strong quenching ability, but there are soft spots on the surface of the workpiece, which are easy to deform and crack.

Salt water: the quenching ability is stronger, the surface of the workpiece is smooth and clean, without soft spots, but it is easier to deform and crack;

Oil: The quenching ability is weak, but the workpiece is not easy to deform and crack

Common quenching cooling method (quench cooling method)

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Temper

Definition: picture

The main purpose of tempering

Eliminate internal stress and reduce brittleness

Stable tissue and workpiece dimensions

Reduce hardness, improve plasticity

Changes in structure and properties of tempering

The structural transformation of quenched steel during tempering mainly occurs in the heating stage. As the heating temperature increases, the structure of quenched steel undergoes four stages of change.

1. Decomposition of martensite

Tempering stage: When tempering at <100°C, the structure does not change; when heating at 100~200°C, martensite will decompose.

Obtained organization: tempered martensite M times (supersaturated α solid solution).

Performance changes: the internal stress gradually decreases, and the performance basically remains the same.

2. Decomposition of retained austenite

Tempering stage: 200-300°C. A' decomposes and transforms into B.

Obtained organization: M (Tempered Martensite) indicates

Performance changes: The stress is further reduced, and the strength and hardness are slightly reduced.

3. The decomposition of martensite is completed and the formation of cementite

Tempering stage: 300-400°C. ε carbides transform into stable cementite.

Obtained organization: Tempered Troostite, represented by T (Tempered Troostite).

Performance changes: the internal stress is basically eliminated, the hardness decreases, and the plastic toughness increases.

4. Fe3C aggregate growth and recovery and recrystallization of α solid solution

Tempering stage: above 400°C. The α phase begins to recover, and recrystallization occurs above 500°C;

Obtained organization: Tempered Sorbite, represented by S (Tempered Sorbite).

Performance changes: good overall performance is obtained.

Microstructure and mechanical properties of tempered steel

craft

tempering temperature

(℃)

Tissue after tempering

Hardness after tempering (HRC)

Features

use

low temperature tempering

150~250

M back

58~64

High hardness, high wear resistance; brittleness, reduced internal stress

tool steel,

Rolling bearings, carburized parts, etc.

Medium temperature tempering

250~500

T back

35~50

Higher elastic limit and yield limit, with certain plasticity and toughness

spring steel,

Hot work mold

high temperature tempering

500~600

S back

25~35

good overall performance

important structural parts

The general trend of mechanical properties changes during tempering: With the increase of tempering temperature, the strength and hardness of steel decrease, and the plasticity and toughness increase.

Surface Heat Treatment (Surface Heat Treatment)

Surface heat treatment: a heat treatment process that only heats the surface of the workpiece to change its structure and properties.

Classification: surface quenching and chemical heat treatment.

In production, there are many parts that require the surface and the core to have different properties. Generally, the surface has high hardness, high wear resistance and fatigue strength; while the core requires better plasticity and toughness.

In this case, starting from material selection alone or using ordinary heat treatment methods cannot meet its requirements. The way to solve this problem is surface heat treatment.

surface quenching

Definition: A heat treatment process that only quenches (+ tempers) the surface of the workpiece

Purpose: To make the surface of the workpiece hard and tough.

Steel for surface hardening: medium carbon structural steel (0.4%-0.5% carbon content)

Methods: surface hardening by induction heating and surface hardening by flame heating.

Induction surface quenching

Basic principle: The induction coil is fed with alternating current → forms an eddy current (skin effect) → obtains A on the surface → obtains M by water cooling.

Classification:

High frequency induction heating:

200~300kHz, 0.5~2.5mm;

Medium frequency induction heating:

0.5~10kHz, 2~10mm;

Power frequency induction heating:

50Hz, 10-20mm.
Rule: The greater the current frequency, the shallower the depth of the hardened layer.

flame heating surface quenching

Definition: Flame heating surface quenching is the application of oxy-acetylene (or other combustible gas) flames to heat the surface of parts and then quench them rapidly. The depth of the hardened layer is generally 2 to 6mm.

Application: suitable for single piece and small batch production.

Chemical heat treatment of steel

Definition: A heat treatment process in which a steel part is kept in an active medium at a certain temperature to allow one or several elements to penetrate into its surface to change its chemical composition, structure and performance.

Classification: According to different infiltrated elements, chemical heat treatment can be divided into carburizing, nitriding, carbonitriding, boronizing, aluminizing, etc.

Basic process:

① Decomposition: Make the chemical medium decompose the active atoms that penetrate into the elements during the heating and heat preservation process;

② Absorption: Active atoms are adsorbed by the surface of the workpiece to form solid solutions or special compounds;

③ Diffusion: The infiltrated atoms diffuse inwardly from the surface of the workpiece to form a diffusion layer with a certain depth, that is, the infiltrated layer

Carburizing of steel (Carburize of steel)

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Purpose: To improve the hardness and wear resistance of the workpiece surface

Steel for carburizing: low carbon steel or low carbon alloy steel

Medium: most commonly used gases (kerosene, benzene, etc.), with activated carbon atoms.

Temperature: in the austenite zone, 900-950°C

Time: Depending on the depth of the seepage layer, about 10 hours.

Other chemical heat treatment methods

Nitriding: A heat treatment process that infiltrates active nitrogen atoms into the surface of a workpiece at a certain temperature. Improve the surface hardness, wear resistance, fatigue strength, thermal hardness and corrosion resistance of parts.

Carbonitriding (carbonitriding): Carbon and nitrogen penetrate into the surface of the workpiece at the same time. Improve surface hardness, fatigue resistance and wear resistance, and combine the advantages of carburizing and nitriding.

Chromizing: It has good corrosion resistance and excellent oxidation resistance, hardness and wear resistance, and can replace stainless steel and heat-resistant steel for tool manufacturing.

Boronizing: very excellent wear resistance, corrosion resistance and mud wear resistance, wear resistance is obviously better than nitriding, carbon and carbonitriding layers, but not resistant to atmospheric and water corrosion. Mainly used for mud pump parts, hot work dies and workpiece fixtures.

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